For drinking now, I have found a number of VERY GOOD 2000 Brunellos. The vintage is not a highly sought after vintage for Brunello, wines seem to be more elegant and feminine but they are drinking very well and are affordable. Try winesearcher.com to find a retailer in your area. I have enjoyed both Casanova di Neri and Piccolomini Ciacci which are generally easier to find.
2003 Brunello is bottled but not yet released and won't be approachable for some time. 2003 Rosso's however are drinking very well and are affordable.
Bordeaux 2000 is excellent but you will pay for it and the best are not really at peak yet.
Hope this helps.